BRAS

Copper Alloys....Brass and Bronze

Brass is an interesting metal, and is as easy as aluminium to cast except that you need to get it hotter.
Understatement of the year, but true, it will produce a degree of zinc fume when melting and of course when molten, and it is unadvisable to hold the metal molten, as zinc will be lost through oxidisation.
I have found that the best way to lower the fuming and retain the zinc is to cover the melt with a layer of BORAX BP I use borax BP. as obtained from a chemist, but any form of borax will work providing there are not additives present.
The borax forms a type of glass that floats on the brass and effectively forms an airtight seal against atmospheric contamination and oxidisation. Depending on what type of metal you start with generally depends on what is left after melting and poring, but I have found that if a good quality "TAP" brass is used, as found in household water taps (Remove the chrome with solution of hydrochloric acid first)
Then the resultant metal will be a little softer and easier to cut, you can add a little lead or plumbers solder to the melt to increase the machinability, but be very careful that you do not add too much, as can cause flaking / cracking of the brass with deposits of lead oxide inside the cavities, but just enough can produce a wonderful machining metal. Some experimentation is required along with careful note taking and weighing of the additives.

You can also add a little tin; this will make the metal harder and too much tin will cause it to shatter and have a white look. Brass or bronzes are fascinating metals, and many different colours, and hues, can be formed from adding different types of brasses and giving it a good stir.

Rule of thumb is that is that no matter what you start with, it will be different on cooling due to the loss of zinc.

Now I have seen various books and journals that state that zinc is toxic, I have also seen that we humans cannot live without zinc, but I cannot find out where the danger point is, there must be a point between what is a recommended safe dally intake, and what is not, need less to say it is not good practice to take huge lungful of zinc fumes and expect to live to over 100, so be careful, brass is much hotter than aluminium and under no circumstances should steel or iron crucibles be used as these may well fail at these higher temperatures

YOU HAVE BEEN WARNED!

The Table below is as good a reference as to what brass can be found in various products and will provide valuable guide as to the type of metal.

Copper alloys, BS numbers, European, CEN & ISO Designations with a brief description on use

 

Alloy Designation

European & ISO designations

Common British Description

Remarks

Availability

BS EN Compositional Designation and Number

Nearest old BS equivalent

   

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Binary Copper-Zinc Alloys                    
CuZn0,5  CW119C     Used for radiator fin strip and for building purposes.            

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CuZn5  CW500L CZ125 Cap copper Industrial use practically confined to caps for ammunition.

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CuZn10  CW501L CZ101 Gilding metal Good corrosion resistance. Used for architectural metalwork and costume jewellery. Can be brazed and enamelled.

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CuZn15  CW502L CZ102 Gilding metal As above. This alloy is used for condenser cooling units, gauges and instrument tubes.

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CuZn20  CW503L CZ103 Ductile brass As above. This alloy has good deep drawing properties.

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CuZn28  CW504L     Suitable for cold deformation.  

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CuZn30  CW505L CZ106 70/30 brass (cartridge brass) In sheet form known as deep drawing brass. As wire, suitable for severe cold deformation.

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CuZn33  CW506L     A good cold working brass.  

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CuZn36  CW507L     General purpose alloy suitable for simple forming.

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CuZn37  CW508L CZ108 Common brass ditto

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CuZn40  CW509L CZ109 60/40 brass Good for hot working. Limited ductility at room temperature.

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Copper-Zinc-Lead Alloys                    
CuZn35Pb1  CW600N     Machinable and has good workability.

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CuZn35Pb2  CW601N     Machinable and has good workability. Used for riveting.

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CuZn36Pb2As  CW602N CZ132 Dezincification resistant brass Good hot ductility. Heat treated to give dezincification resistance.

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CuZn36Pb3  CW603N CZ124 Free cutting brass Excellent machinability but very limited cold workability.

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CuZn37Pb0,5  CW604N     Machinable and has some cold workability.

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CuZn37Pb1  CW605N     Machinable and has good to very good cold workability.

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CuZn37Pb2  CW606N CZ119/131 Free cutting brass with improved ductility Good machinability, some cold workability. Used for cold heading and riveting.  

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CuZn38Pb1  CW607N CZ129   Machinable and has good to very good cold workability

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CuZn38Pb2  CW608N CZ128 Free cutting brass Good machinability, sufficient ductility for some cold work.

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CuZn38Pb4  CW609N CZ121Pb4 High speed machining brass Extra high machining speeds but very limited cold workability. Also used for hot stamping.  

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CuZn39Pb0,5  CW610N CZ137   Machinable and has some workability.  

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CuZn39Pb1  CW611N CZ129 Free cutting brass with improved ductility Commonly used for hot stamping. Machinable and good workability.  

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CuZn39Pb2  CW612N CZ120/128 Free cutting brass with improved ductility Good machinability, some cold workability but lower than that of CZ131.  

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CuZn39Pb2Sn  CW613N     Similar to CZ128 but with higher permitted impurity level. Unsuitable for machining at highest speeds.  

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CuZn39Pb3  CW614N CZ121Pb3 High speed machining brass Excellent machinability, very limited cold workability. Also used for hot stamping.

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CuZn39Pb3Sn  CW615N     Similar to CZ121Pb3 but with higher permitted impurity level. Unsuitable for machining at highest speeds.        

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CuZn40Pb1Al  CW616N     Forging brass. The aluminium gives an attractive colour and eases extraction from the dies.        

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CuZn40Pb2  CW617N CZ122 Free cutting brass Most popular alloy for hot stamping. Excellent machinability but very limited cold ductility compared with alloys also containing 2%Pb but with higher copper content.

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CuZn40Pb2Al  CW618N   Brass for architectural sections Good bright yellow colour for architectural profiles. The higher the zinc content the more complex the profiles achievable.    

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CuZn40Pb2Sn  CW619N     Similar to CZ122 but with higher permitted impurity level. Unsuitable for machining at highest speeds.  

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CuZn41Pb1Al  CW620N     Production of complex profiles by hot extrusion.    

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CuZn42PbAl CW621N

    Production of complex profiles by hot extrusion.    

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CuZn43Pb1Al CW622N

    Production of complex profiles by hot extrusion.    

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CuZn43Pb2 CW623N CZ130   Production of complex profiles by hot extrusion. Aluminium free.

(The British Standard CZ130 covers aluminium contents from 0 to 0.5%)

   

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CuZn43Pb2Al  CW624N CZ130   Good bright yellow colour for architectural profiles. The higher the zinc content the more complex the profiles achievable.    

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COMPLEX COPPER-ZINC ALLOYS                    
CuZn13Al1Ni1Si1CW700R     Special tubes.

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CuZn19Sn  CW701R   205 Brass Good corrosion resistance and hardness. Used for scouring pads.      

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CuZn20Al2A  CW702R CZ110 Aluminium Brass Excellent corrosion resistance in clean seawater and is a favoured alloy for condenser tubes.

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CuZn23Al3C  CW703R     Used for springs and connectors.            

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CuZn23Al6Mn4Fe3Pb  CW704R        

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CuZn25Al5Fe2Mn2Pb  CW705R CZ116 High tensile brass High strength and good corrosion resistance.  

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CuZn31Si1  CW708R     General purpose alloy produced as rod and tube.  

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CuZn32Pb2AsFeSi  CW709R     Dezincification resistant brass of Swedish origin.

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CuZn35Ni3Mn2AlPb  CW710R      

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CuZn36Pb2Sn1  CW711R CZ134 Leaded naval brass Tin addition improves corrosion resistance especially in sea water. Lead improves machinability.  

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CuZn38Sn1Pb  CW712R CZ112 Leaded naval brass Tin addition improves corrosion resistance especially in sea water. Lead improves machinability.  

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CuZn37Mn3Al2PbS iCW713R CZ135 High tensile brass with silicon Silicon addition gives extra wear and galling resistance to suit applications such as gear box components.

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CuZn37Pb1Sn1  CW714R        

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CuZn38AlFeNiPbSn  CW715R                

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CuZn38Mn1Al  CW716R        

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CuZn39Mn1AlPbSi  CW718R     Silicon and manganese additions give good wear resistance for gear box components and bearings.

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CuZn39Sn1  CW719R CZ133 Naval brass Tin addition improves corrosion resistance especially in sea water.  

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CuZn40Mn1Pb1  CW720R CZ136 Manganese containing brass Excellent resistance to seizure. Used in contact with cast iron. Used for architectural profiles. Attractive chocolate brown oxide.  

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CuZn40Mn1Pb1AlFeSn  CW721R CZ114 High tensile brass General purpose high strength alloy.  

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CuZn40Mn1Pb1FeSn  CW722R CZ115 High tensile brass Aluminium free, used where components are to be joined by soldering or brazing.  

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CuZn40Mn2Fe1  CW723R     General purpose high strength alloy.

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COPPER-NICKEL-ZINC ALLOYS                    
CuNi7Zn39Pb3Mn2  CW400J          

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CuNi10Zn27  CW401J NS103 10% nickel silver        

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CuNi10Zn42Pb2  CW402J NS101 Leaded 10% nickel brass      

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CuNi12Zn24  CW403J NS104 12% nickel silver Good spring properties.

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CuNi12Zn25Pb1  CW404J     Lead addition improves machinability.          

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CuNi12Zn29  CW405J     This alloy contains no lead and is only available as strip.            

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CuNi12Zn30Pb1  CW406J     This alloy is also used for extrusions.    

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CuNi12Zn38Mn5Pb2  CW407J          

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CuNi18Zn19Pb1  CW408J NS113        

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CuNi18Zn20  CW409J NS106 18% nickel silver The whitest of the nickel silvers with optimum corrosion resistance.

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CuNi18Zn27  CW410J     This alloy contains no lead and is only available as strip.          

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