Copper Alloys....Brass and Bronze
Brass is an interesting metal, and is as easy as aluminium to cast except
that you need to get it hotter.
Understatement of the year, but true, it will
produce a degree of zinc fume when melting and of course when molten, and it is
unadvisable to hold the metal molten, as zinc will be lost through
oxidisation.
I have found that the best way to lower the fuming and retain
the zinc is to cover the melt with a layer of BORAX BP I use borax BP. as
obtained from a chemist, but any form of borax will work providing there are not
additives present.
The borax forms a type of glass that floats on the brass and
effectively forms an airtight seal against atmospheric contamination and
oxidisation. Depending on what type of metal you start with generally depends on
what is left after melting and poring, but I have found that if a good quality "TAP" brass is used, as found in household water taps (Remove the chrome with solution of hydrochloric acid
first)
Then the resultant metal will be a little softer and easier to cut,
you can add a little lead or plumbers solder to the melt to increase the machinability, but be very
careful that you do not add too much, as can cause flaking / cracking of the
brass with deposits of lead oxide inside the cavities, but just enough can
produce a wonderful machining metal. Some experimentation is required along with
careful note taking and weighing of the additives.
You can also add a little tin; this will make the metal harder and too much tin will cause it to shatter and have a white look. Brass or bronzes are fascinating metals, and many different colours, and hues, can be formed from adding different types of brasses and giving it a good stir.
Rule of thumb is that is that no matter what you start with, it will be different on cooling due to the loss of zinc.
Now I have seen various books and journals that state that zinc is toxic, I have also seen that we humans cannot live without zinc, but I cannot find out where the danger point is, there must be a point between what is a recommended safe dally intake, and what is not, need less to say it is not good practice to take huge lungful of zinc fumes and expect to live to over 100, so be careful, brass is much hotter than aluminium and under no circumstances should steel or iron crucibles be used as these may well fail at these higher temperatures
YOU HAVE BEEN WARNED!
The Table below is as good a reference as to what brass can be found in various products and will provide valuable guide as to the type of metal.
Copper alloys, BS numbers, European, CEN & ISO Designations with a brief description on use
|
Alloy Designation European & ISO designations |
Common British Description |
Remarks |
Availability |
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|
BS EN Compositional Designation and Number |
Nearest old BS equivalent |
Tube |
Rod |
Profiles |
Wire |
Forgings |
Plate&Sheet |
Strip |
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| Binary Copper-Zinc Alloys | ||||||||||
| CuZn0,5 CW119C | Used for radiator fin strip and for building purposes. | Strip |
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| CuZn5 CW500L | CZ125 | Cap copper | Industrial use practically confined to caps for ammunition. | Tube |
Rod |
Plate&Sheet |
Strip |
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| CuZn10 CW501L | CZ101 | Gilding metal | Good corrosion resistance. Used for architectural metalwork and costume jewellery. Can be brazed and enamelled. | Tube |
Rod |
Wire |
Plate&Sheet |
Strip |
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| CuZn15 CW502L | CZ102 | Gilding metal | As above. This alloy is used for condenser cooling units, gauges and instrument tubes. | Tube |
Rod |
Wire |
Plate&Sheet |
Strip |
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| CuZn20 CW503L | CZ103 | Ductile brass | As above. This alloy has good deep drawing properties. | Tube |
Rod |
Wire |
Plate&Sheet |
Strip |
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| CuZn28 CW504L | Suitable for cold deformation. | Rod |
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| CuZn30 CW505L | CZ106 | 70/30 brass (cartridge brass) | In sheet form known as deep drawing brass. As wire, suitable for severe cold deformation. | Tube |
Rod |
Wire |
Plate&Sheet |
Strip |
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| CuZn33 CW506L | A good cold working brass. | Rod |
Plate&Sheet |
Strip |
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| CuZn36 CW507L | General purpose alloy suitable for simple forming. | Tube |
Rod |
Profiles |
Wire |
Plate&Sheet |
Strip |
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| CuZn37 CW508L | CZ108 | Common brass | ditto | Tube |
Rod |
Profiles |
Wire |
Forgings |
Plate&Sheet |
Strip |
| CuZn40 CW509L | CZ109 | 60/40 brass | Good for hot working. Limited ductility at room temperature. | Tube |
Rod |
Profiles |
Forgings |
Plate&Sheet |
Strip |
|
| Copper-Zinc-Lead Alloys | ||||||||||
| CuZn35Pb1 CW600N | Machinable and has good workability. | Tube |
Rod |
Profiles |
Wire |
Plate&Sheet |
Strip |
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| CuZn35Pb2 CW601N | Machinable and has good workability. Used for riveting. | Tube |
Rod |
Profiles |
Wire |
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| CuZn36Pb2As CW602N | CZ132 | Dezincification resistant brass | Good hot ductility. Heat treated to give dezincification resistance. | Tube |
Rod |
Profiles |
Forgings |
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| CuZn36Pb3 CW603N | CZ124 | Free cutting brass | Excellent machinability but very limited cold workability. | Tube |
Rod |
Profiles |
Wire |
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| CuZn37Pb0,5 CW604N | Machinable and has some cold workability. | Tube |
Plate&Sheet |
Strip |
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| CuZn37Pb1 CW605N | Machinable and has good to very good cold workability. | Tube |
Rod |
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| CuZn37Pb2 CW606N | CZ119/131 | Free cutting brass with improved ductility | Good machinability, some cold workability. Used for cold heading and riveting. | Rod |
Profiles |
Wire |
Plate&Sheet |
Strip |
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| CuZn38Pb1 CW607N | CZ129 | Machinable and has good to very good cold workability | Tube |
Rod |
Profiles |
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| CuZn38Pb2 CW608N | CZ128 | Free cutting brass | Good machinability, sufficient ductility for some cold work. | Tube |
Rod |
Profiles |
Wire |
Forgings |
Plate&Sheet |
Strip |
| CuZn38Pb4 CW609N | CZ121Pb4 | High speed machining brass | Extra high machining speeds but very limited cold workability. Also used for hot stamping. | Rod |
Profiles |
Wire |
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| CuZn39Pb0,5 CW610N | CZ137 | Machinable and has some workability. | Rod |
Profiles |
Wire |
Forgings |
Plate&Sheet |
Strip |
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| CuZn39Pb1 CW611N | CZ129 | Free cutting brass with improved ductility | Commonly used for hot stamping. Machinable and good workability. | Rod |
Profiles |
Forgings |
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| CuZn39Pb2 CW612N | CZ120/128 | Free cutting brass with improved ductility | Good machinability, some cold workability but lower than that of CZ131. | Rod |
Profiles |
Wire |
Forgings |
Plate&Sheet |
Strip |
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| CuZn39Pb2Sn CW613N | Similar to CZ128 but with higher permitted impurity level. Unsuitable for machining at highest speeds. | Rod |
Profiles |
Forgings |
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| CuZn39Pb3 CW614N | CZ121Pb3 | High speed machining brass | Excellent machinability, very limited cold workability. Also used for hot stamping. | Tube |
Rod |
Profiles |
Wire |
Forgings |
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| CuZn39Pb3Sn CW615N | Similar to CZ121Pb3 but with higher permitted impurity level. Unsuitable for machining at highest speeds. | Forgings |
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| CuZn40Pb1Al CW616N | Forging brass. The aluminium gives an attractive colour and eases extraction from the dies. | Forgings |
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| CuZn40Pb2 CW617N | CZ122 | Free cutting brass | Most popular alloy for hot stamping. Excellent machinability but very limited cold ductility compared with alloys also containing 2%Pb but with higher copper content. | Tube |
Rod |
Profiles |
Wire |
Forgings |
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| CuZn40Pb2Al CW618N | Brass for architectural sections | Good bright yellow colour for architectural profiles. The higher the zinc content the more complex the profiles achievable. | Profiles |
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| CuZn40Pb2Sn CW619N | Similar to CZ122 but with higher permitted impurity level. Unsuitable for machining at highest speeds. | Rod |
Profiles |
Forgings |
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| CuZn41Pb1Al CW620N | Production of complex profiles by hot extrusion. | Profiles |
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| CuZn42PbAl CW621N | Production of complex profiles by hot extrusion. | Profiles |
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| CuZn43Pb1Al CW622N | Production of complex profiles by hot extrusion. | Profiles |
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| CuZn43Pb2 CW623N | CZ130 | Production of complex profiles by
hot extrusion. Aluminium free.
(The British Standard CZ130 covers aluminium contents from 0 to 0.5%) |
Profiles |
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| CuZn43Pb2Al CW624N | CZ130 | Good bright yellow colour for architectural profiles. The higher the zinc content the more complex the profiles achievable. | Profiles |
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| COMPLEX COPPER-ZINC ALLOYS | ||||||||||
| CuZn13Al1Ni1Si1CW700R | Special tubes. | Tube |
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| CuZn19Sn CW701R | 205 Brass | Good corrosion resistance and hardness. Used for scouring pads. | Wire |
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| CuZn20Al2A CW702R | CZ110 | Aluminium Brass | Excellent corrosion resistance in clean seawater and is a favoured alloy for condenser tubes. | Tube |
Plate&Sheet |
Strip |
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| CuZn23Al3C CW703R | Used for springs and connectors. | Strip |
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| CuZn23Al6Mn4Fe3Pb CW704R | Rod |
Forgings |
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| CuZn25Al5Fe2Mn2Pb CW705R | CZ116 | High tensile brass | High strength and good corrosion resistance. | Rod |
Forgings |
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| CuZn31Si1 CW708R | General purpose alloy produced as rod and tube. | Rod |
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| CuZn32Pb2AsFeSi CW709R | Dezincification resistant brass of Swedish origin. | Tube |
Rod |
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| CuZn35Ni3Mn2AlPb CW710R | Tube |
Rod |
Profiles |
Forgings |
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| CuZn36Pb2Sn1 CW711R | CZ134 | Leaded naval brass | Tin addition improves corrosion resistance especially in sea water. Lead improves machinability. | Rod |
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| CuZn38Sn1Pb CW712R | CZ112 | Leaded naval brass | Tin addition improves corrosion resistance especially in sea water. Lead improves machinability. | Rod |
Profiles |
Wire |
Forgings |
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| CuZn37Mn3Al2PbS iCW713R | CZ135 | High tensile brass with silicon | Silicon addition gives extra wear and galling resistance to suit applications such as gear box components. | Tube |
Rod |
Profiles |
Forgings |
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| CuZn37Pb1Sn1 CW714R | Rod |
Profiles |
Wire |
Forgings |
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| CuZn38AlFeNiPbSn CW715R | Plate&Sheet |
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| CuZn38Mn1Al CW716R | Rod |
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| CuZn39Mn1AlPbSi CW718R | Silicon and manganese additions give good wear resistance for gear box components and bearings. | Tube |
Rod |
Profiles |
Forgings |
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| CuZn39Sn1 CW719R | CZ133 | Naval brass | Tin addition improves corrosion resistance especially in sea water. | Rod |
Profiles |
Forgings |
Plate&Sheet |
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| CuZn40Mn1Pb1 CW720R | CZ136 | Manganese containing brass | Excellent resistance to seizure. Used in contact with cast iron. Used for architectural profiles. Attractive chocolate brown oxide. | Rod |
Profiles |
Wire |
Forgings |
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| CuZn40Mn1Pb1AlFeSn CW721R | CZ114 | High tensile brass | General purpose high strength alloy. | Rod |
Profiles |
Forgings |
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| CuZn40Mn1Pb1FeSn CW722R | CZ115 | High tensile brass | Aluminium free, used where components are to be joined by soldering or brazing. | Rod |
Profiles |
Forgings |
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| CuZn40Mn2Fe1 CW723R | General purpose high strength alloy. | Tube |
Rod |
Profiles |
Forgings |
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| COPPER-NICKEL-ZINC ALLOYS | ||||||||||
| CuNi7Zn39Pb3Mn2 CW400J | Profiles |
Wire |
Forgings |
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| CuNi10Zn27 CW401J | NS103 | 10% nickel silver | Wire |
Plate&Sheet |
Strip |
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| CuNi10Zn42Pb2 CW402J | NS101 | Leaded 10% nickel brass | Profiles |
Wire |
Forgings |
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| CuNi12Zn24 CW403J | NS104 | 12% nickel silver | Good spring properties. | Tube |
Rod |
Profiles |
Wire |
Plate&Sheet |
Strip |
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| CuNi12Zn25Pb1 CW404J | Lead addition improves machinability. | Plate&Sheet |
Strip |
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| CuNi12Zn29 CW405J | This alloy contains no lead and is only available as strip. | Strip |
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| CuNi12Zn30Pb1 CW406J | This alloy is also used for extrusions. | Profiles |
Wire |
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| CuNi12Zn38Mn5Pb2 CW407J | Profiles |
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| CuNi18Zn19Pb1 CW408J | NS113 | Profiles |
Wire |
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| CuNi18Zn20 CW409J | NS106 | 18% nickel silver | The whitest of the nickel silvers with optimum corrosion resistance. | Tube |
Rod |
Profiles |
Wire |
Plate&Sheet |
Strip |
|
| CuNi18Zn27 CW410J | This alloy contains no lead and is only available as strip. | Plate&Sheet |
Strip |
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